Cas 76334-17-3,triphenylphosphine-hexaborane<sup>(10)</sup>

76334-17-3

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Basic information

Product Name: triphenylphosphine-hexaborane⁽¹⁰⁾
Synonyms:
CAS NO:76334-17-3
Molecular Formula:
Molecular Weight: 337.236
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: triphenylphosphine-hexaborane⁽¹⁰⁾(CAS DataBase Reference)
NIST Chemistry Reference: triphenylphosphine-hexaborane⁽¹⁰⁾(76334-17-3)
EPA Substance Registry System: triphenylphosphine-hexaborane⁽¹⁰⁾(76334-17-3)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 76334-17-3(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 76334-17-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,6,3,3 and 4 respectively; the second part has 2 digits, 1 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 76334-17:
(7*7)+(6*6)+(5*3)+(4*3)+(3*4)+(2*1)+(1*7)=133
133 % 10 = 3
So 76334-17-3 is a valid CAS Registry Number.

76334-17-3Upstream product

23777-80-2 hexaborane⁽¹⁰⁾

76334-17-3Downstream Products

76334-17-3Relevant academic research and scientific papers

Formation of the 1:1 phosphine adducts of hexaborane(10)

Kameda, Mitsuaki,Kodama, Goji

, p. 1072 - 1074 (1981)

The formation of trimethylphosphine-hexaborane(10) in the reaction of hexaborane(10) with trimethylphosphine was confirmed. The compound is stable below -20°C in dichloromethane or in tetrahydrofuran and reacts with trimethylphosphine to give bis(trimethylphosphine)-hexaborane(10). Triphenylphosphine adds to hexaborane(10) likewise to form B6H10·P(C6H5)3. On the basis of the 11B and 1H NMR spectra, a B5H8- derivative structure is proposed for the 1:1 adducts. A mechanism for the conversion of the pyramid-shaped B6H10 framework to the belt-shaped structure of B6H10·2P(CH3)3 is discussed.

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