76358-71-9

Basic information

• Product Name: 3-iodo-2,3-dimethyl-2-butyl tert-butyldiphenylsilyl ether
• Synonyms: 3-iodo-2,3-dimethyl-2-butyl tert-butyldiphenylsilyl ether
• CAS NO: 76358-71-9
• Molecular Weight: 466.478
• Mol File: 76358-71-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-iodo-2,3-dimethyl-2-butyl tert-butyldiphenylsilyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: 3-iodo-2,3-dimethyl-2-butyl tert-butyldiphenylsilyl ether(76358-71-9)
• EPA Substance Registry System: 3-iodo-2,3-dimethyl-2-butyl tert-butyldiphenylsilyl ether(76358-71-9)

Safety Data

• Hazardous Substances Data: 76358-71-9(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 76358-44-6 tBuPh₂SiSePh 
• 5076-20-0 2,3-dimethyl-2,3-epoxybutane 
• 76358-46-8 tert-butyldiphenylsilyl iodide 

Downstream Products

• 76358-72-0 2,3-dimethylbut-3-en-2-yl tert-butyldiphenylsilyl ether 

Relevant articles and documents

Silyl Halides from (Phenylseleno)silanes. Reaction with Oxiranes and Alcohols To Give Hydrolytically Stable Silyl Ethers.

The preparation of (phenylseleno)silanes and their reactions with halogens (Cl2, Br2, I2) to give silyl halides and diphenyl diselenide are described.Highly hindered tert-butyldimethyl and tert-butyl diphenylsilyl halides were easily prepared.The reaction of silyl bromides and iodides with oxiranes followed by diazabicyclononane treatment gave allylic alcohol silyl ethers.Tertiary alcohols reacted rapidly with silyliodides to give hydrolytically stable silyl ethers.Treatment of the silyl ethers with tetra-n-butylammonium fluoride gave the free alcohols withoutrearrangement or isomerization.