76370-44-0Relevant academic research and scientific papers
Palladium-catalyzed highly diastereoselective cyclic carbopalladation-carbonylative esterification tandem reaction of iododienes and iodoarylalkenes
Cope?ret, Christophe,Negishi, Ei-Ichi
, p. 165 - 167 (2008/03/11)
(Equation Presented) Pd-catalyzed reaction of iododienes and iodoarylalkenes represented by 1, 8, and 10 under 1 atm of CO and a small amount of O2 in the presence of a base, e.g., NEt3, as well as MeOH and H2O in DMF can
SYNTHESIS OF 4,4-DISUBSTITUTED CYCLOHEXENONES. PART 1. BAEYER-VILLIGER FRAGMENTATION OF 1-METHOXYBICYCLOOCT-5-ENONES.
Holmes, Andrew B.,Madge, Nigel C.
, p. 789 - 802 (2007/10/02)
The sodium acetate-buffered peracetic acid oxidation of various 1-methoxybicyclooct-5-enones (4a-f), and (14), prepared by hydrolysis of the adducts (3) derived from dihydroanisole derivatives (2) and 2-chloroacrylonitrile leads to 4-
Synthesis of 4,4-Disubstituted Cyclohexenones by the Baeyer-Viliger Fragmentation of 1-Methoxybicyclooct-5-enones
Madge, Nigel C.,Holmes, Andrew B.
, p. 956 - 957 (2007/10/02)
The sodium acetate-buffered, peracetic acid oxidation of various 1-methoxybicyclooct-5-enones, prepared by hydrolysis of the adducts derived from dihydroanisole derivatives and α-chloroacrylonitrile, leads to 4-substituted cyclohex-2-en-1-one 4-acetic acid derivatives.
