76371-39-6Relevant academic research and scientific papers
DAST-mediated regioselective anomeric group migration in saccharides
Lin, Po-Chiao,Adak, Avijit Kumar,Ueng, Shau-Hua,Huang, Li-De,Huang, Kuo-Ting,Ho, Ja-An Annie,Lin, Chun-Cheng
scheme or table, p. 4041 - 4048 (2009/09/08)
(Chemical Equation Presented) When saccharides bearing a sulfur, selenium, or oxygen substituent at the anomeric center and an unprotected hydroxyl group either at C-4 or C-6 were subjected to fluorination with DAST in dichloromethane, a regioselective mi
Palladium chloride mediated rearrangement of 6-deoxyhex-5-enopyranosides into cyclohexanones
Iimori, Takamasa,Takahashi, Hideyo,Ikegami, Shiro
, p. 649 - 652 (2007/10/02)
PdCl2 was found to mediate the Ferrier rearrangement of broad range of substrates catalytically in neutral conditions. In this reaction, the stereoselectivity of newly formed chiral center was controlled by the hydroxyl protective groups on the starting sugar moiety and was rationally explained by the consideration of chair like conformations.
Unsaturated Carbohydrates. Part 28. Observations on the Conversion of 6-Deoxyhex-5-enopyranosyl Compounds into 2-Deoxyinosose Derivatives
Blattner, Regine,Ferrier, Robert J.,Haines, Stephen R.
, p. 2413 - 2416 (2007/10/02)
Mercury-containing intermediates have been isolated from the reaction of 6-deoxyhex-5-enopyranosyl compounds with mercury(II) salts in aqueous acetone.They react to give 2-deoxyinosose derivatives on further exposure to the conditions of their formation o
New Approach to Aminoglycoside Antibiotics
Blattner, Regine,Ferrier, Robert J.,Prasit, Petpiboon
, p. 944 - 945 (2007/10/02)
Photobromination of peracylated hexopyranoses and treatment of the resultant 5-bromo-derivatives with zinc and acetic acid afforded 6-deoxy-5-enose esters which, with mercury(II) salts in aqueous media, gave 2-deoxyinosose triesters; applied to β-D-maltos
