76371-51-2

Basic information

• Product Name: Bromo-dichloro-phenyl-silane
• Synonyms: Bromo-dichloro-phenyl-silane
• CAS NO: 76371-51-2
• Molecular Weight: 256.001
• Mol File: 76371-51-2.mol

Chemical Properties

• CAS DataBase Reference: Bromo-dichloro-phenyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: Bromo-dichloro-phenyl-silane(76371-51-2)
• EPA Substance Registry System: Bromo-dichloro-phenyl-silane(76371-51-2)

Safety Data

• Hazardous Substances Data: 76371-51-2(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 

Relevant articles and documents

ONE-STEP REGIOSPECIFIC SYNTHESIS OF ALLYLIC SILANES - EXTENSION TO BENZYLSILANES

Allyltrichlorosilanes are prepared according to a one-step regiospecific process based on the reaction of allyl chlorides with SiCl4 and NiCp2/HMPA (catalyst), in the presence of industrial methylchlorodisilane fraction.Benzyltrihalosilanes are similarly obtained.

SOME PRACTICAL USES OF THE DISILANE RESIDUE FROM THE DIRECT SYNTHESIS OF METHYLCHLOROSILANES

Some practical uses for the disilane residue from the direct synthesis of methylchlorosilanes have been proposed.This residue can be converted into organochloro-(Me2SiCl2, MeSiCl3, Me3SiCl) or organohydrochloro-monosilanes (HMeSiCl2, HMe2SiCl).These disilanes can also be used for the synthesis of alkyl (haloalkyl, alkenyl, aryl, etc.) methyldichlorosilanes or alkyl (haloalkyl, alkenyl, aryl, etc.) trichlorosilanes.The reductive properties of the Si-Si bond of these species have been utilized (e.g. in the reduction of phosphine oxides into the corresponding phosphines).Polysilanes resulting from the disproportionation of this residue are precursors of polycarbosilanes.