763901-71-9Relevant academic research and scientific papers
Peptide-metal complex as an asymmetric catalyst. A catalytic enantioselective cyanohydrin synthesis
Mori,Nitta,Kudo,Inoue
, p. 4333 - 4336 (1991)
An acyclic dipeptide ester, 2-hydroxy-1-naphthylideneimino-(S)-valyl-(S)-tryptophane methyl ester (1a: Nap-S-Val-S-Trp-OMe), whose terminal amino group is modified to a Schiff base, is designed as a chiral auxiliary of an asymmetric catalyst. The mixture of 1 with titanium alkoxide catalyzes enantioselective hydrocyanation of benzaldehyde to afford optically active (R)-mandelonitrile with stereoselectivities up to 96:6.
