76395-46-5Relevant academic research and scientific papers
A single-step one pot synthesis of O,O′-dialkyl N,N-dialkylphosphoramidates from dialkylphosphites
Purohit, Ajay Kumar,Pardasani, Deepak,Kumar, Ajeet,Goud, D. Raghavender,Jain, Rajiv,Dubey
, p. 3754 - 3756 (2016)
An efficient synthetic method has been developed to obtain chemical weapons convention (CWC)-related O,O′-dialkyl-N,N-dialkylphosphoramidates from dialkylphosphites using inorganic reagents (CuCl2and Cs2CO3) at room temperature.
Dichlorodimethyl hydantoin: An efficient reagent for one-pot synthesis of CWC-related O,O-dialkyl, N,N-dialkyl phosphoramidates
Gupta, Arvind K.,Dubey, Devendra K.,Kaushik
scheme or table, p. 1641 - 1658 (2009/06/18)
A simple, rapid, economical, and efficient one-pot synthetic method for preparation of O,O-dialkyl, N,N-dialkylphosphoramidates (DADAPs) and phosphates has been developed. Copyright Taylor & Francis Group, LLC.
N,N′-dichlorobis(2,4,6-trichlorophenyl)urea (CC-2): An efficient reagent for the synthesis of chemical weapons convention-related dialkyl-N,N-dialkylphosphoramidates from dialkylphosphites
Gupta, Arvind K.,Pardasani, Deepak,Gupta, Hemendra K.,Dubey, Devendra K.
, p. 879 - 882 (2008/09/16)
The present paper describes the one-pot synthesis of dialkyl N,N-dialkylphosphoramidates (DADAP) from dialkylphosphites and dialkylamines using N,N?-dichlorobis(2,4,6-trichlorophenyl)urea (CC-2) as chlorinating reagent. DADAP belong to the schedule 2.B.6 category of the Chemical Weapons Convention (CWC), as they are the important markers of the chemical warfare agent tabun and its analogues. The study was undertaken to develop the spectral database of DADAP for verification of CWC. The reported synthetic strategy can be adopted to rapidly synthesize several analogues of DADAP during official proficiency tests. CSIRO 2007.
PERACID AND ACYL PEROXY RADICAL MEDIATED OXIDATION AND REARRANGEMENT OF PHOSPHORAMIDES
Davidson, R. Stephen,Walker, Martin D.
, p. 305 - 310 (2007/10/02)
Acyl peroxy radicals can cause oxidation of sulphur at pentavalent phosphorus and can also affect the decomposition of phosphoramides.Peracids can also oxidise thiophosphorus compounds to their respective oxidised phosphorus analogues and oxidise phosphoramides via N-oxidation.
