76430-21-2

Basic information

• Product Name: methyl 3,3-dimethyl-4,5,5-tricyano-4-pentenoate
• Synonyms: methyl 3,3-dimethyl-4,5,5-tricyano-4-pentenoate
• CAS NO: 76430-21-2
• Molecular Weight: 217.227
• Mol File: 76430-21-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 3,3-dimethyl-4,5,5-tricyano-4-pentenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3,3-dimethyl-4,5,5-tricyano-4-pentenoate(76430-21-2)
• EPA Substance Registry System: methyl 3,3-dimethyl-4,5,5-tricyano-4-pentenoate(76430-21-2)

Safety Data

• Hazardous Substances Data: 76430-21-2(Hazardous Substances Data)

Upstream product

• 76430-13-2 2,2,3,3-tetracyano-4,4-dimethylcyclopentanone dimethyl acetal 

Relevant articles and documents

Cycloaddition of cyclopropanone acetals to tetracyanoethylene

The cyclopropanone acetals 1a-e and tetracyanoethylene give in a thermal [σ2 + π2] cycloaddition 2,2,3,3-tetracyanocyclopentanone acetals 2a-e. In the case of 2-methylcyclopropanone acetal 1c the corresponding 5-methylcyclopentanone acetal 3c is also formed in minor amounts. With respect to the parent compound methyl substituents in the cyclopropane ring (1b-c,e) retard the cycloaddition reaction, whereas a phenyl group (1d) accelerates the reaction. The cycloadducts 2 are converted by water mainly into the ring-opened esters 4. The structures of compound 2 have been determined by 1H and 13C NMR.