76436-52-7

Upstream product

• 76436-50-5 (1S,4aS,5S,8aR)-1-Benzyl-5-hydroxy-1,4a-dimethyl-octahydro-naphthalen-2-one 
• 24138-10-1 (+/-)-(4aβ,5β)-4,4a,5,6,7,8-hexahydro-5-hydroxy-1,4a-dimethylnaphthalen-2(3H)-one 
• 76436-50-5 trans-octahydro-1α-benzyl-1β,4aβ-dimethyl-5β-hydroxy-2(1H)-naphthalenone 
• 76436-51-6 trans-decahydro-5α-benzyl-5β,8aβ-dimethyl-6-methylene-1-naphthalenol 
• 38405-15-1 (4aS,5S)-4,4a,5,6,7,8-hexahydro-5-hydroxy-1,4a-dimethylnaphthalen-2(3H)-one 
• 76436-51-6 (1S,4aS,5S,8aS)-5-Benzyl-5,8a-dimethyl-6-methylene-decahydro-naphthalen-1-ol 

Relevant academic research and scientific papers

Synthetic Studies of trans-Clerodane Diterpenoids and Congeners: Stereocontrolled Total Synthesis of (+/-)-Avarol

A stereocontrolled total synthesis of (+/-)-avarol, a sesquiterpenoid hydroquinone, has been accomplished in eight steps, by a flexible route which is potentially useful in the synthesis of related natural products containing a functionalized bicyclo4.4.

STUDIES TOWARDS THE SYNTHESIS OF TRANS-CLERODANE DITERPENES AND CONGENERS: STEREOSELECTIVE SYNTHESIS OF (+/-)-4aβ,7β,8β,-TRIMETHYL-8α-BENZYL-4β-HYDROXY-TRANS-DECALIN

A stereoselective synthesis of the title compound (5), by a route which allows flexibility for an approach to trans-clerodane diterpenes and congeners, is discribed.