764583-34-8Relevant academic research and scientific papers
Palladium-Catalyzed Remote ortho-C-H Alkenylation of Alkyl Aryl Sulfones: Access to Densely Functionalized Indane Derivatives
Legarda, Pablo D.,García-Rubia, Alfonso,Gómezarrayás, Ramón,Carretero, Juan C.
supporting information, p. 1065 - 1072 (2016/04/19)
A practical method for the palladium-catalyzed ortho-olefination of benzyl and phenethyl 2-pyridyl sulfones with electron-deficient alkenes using N-fluoro-2,4,6-trimethylpyridinium triflate ([F+]) as the terminal oxidant is described. The chela
Enantioselective synthesis of chiral sulfones by Rh-catalyzed asymmetric addition of boronic acids to α,β-unsaturated 2-pyridyl sulfones
Mauleon, Pablo,Alonso, Ines,Rivero, Marta Rodriguez,Carretero, Juan C.
, p. 9924 - 9935 (2008/03/28)
(Chemical Equation Presented) A general and efficient method for the rhodium-catalyzed enantioselective catalytic conjugate addition of organoboronic acids to α,β-unsaturated sulfones is described. The success of the process relies on the use of α,β-unsat
Catalytic asymmetric conjugate reduction of β,β-disubstituted α,β-unsaturated sulfones
Llamas, Tomas,Arrayas, Ramon Gomez,Carretero, Juan C.
, p. 3329 - 3332 (2008/03/12)
(Chemical Equation Presented) Access to a chiral sulfone: Asymmetric conjugate reduction of β,β-disubstituted α,β-unsaturated 2-pyridylsulfones with silanes under CuI/binap catalysis provides chiral sulfones with excellent chemical yields and e
Rhodium-catalyzed enantioselective conjugate addition of organoboronic acids to α,β-unsaturated sulfones
Mauleon, Pablo,Carretero, Juan C.
, p. 3195 - 3198 (2007/10/03)
(Chemical Equation Presented) A general method for the enantioselective catalytic conjugate addition to acyclic α,β-unsaturated sulfones is described. Using metal-chelating α,β-unsaturated pyridyl sulfones as substrates, the rhodium-catalyzed chiraphos-me
