76489-56-0

Upstream product

• 870-63-3 prenyl bromide 
• 141330-17-8 3-<2,4-Bis(methoxymethoxy)phenyl>-1-<2-hydroxy-4-(methoxymethoxy)phenyl>prop-2-en-1-on 
• 74-88-4 methyl iodide 
• 56075-16-2 2,4-Dimethoxy-3-C-prenylacetophenone 
• 613-45-6 2,4-Dimethoxybenzaldehyde 
• 76502-88-0 [(1S,2R,6R)-2-[2,6-Dimethoxy-4-(6-methoxy-benzofuran-2-yl)-phenyl]-6-(2,4-dimethoxy-phenyl)-4-methyl-cyclohex-3-enyl]-[2,4-dimethoxy-3-(3-methyl-but-2-enyl)-phenyl]-methanone 
• 76851-98-4 8-[(1S,5R,6S)-6-[2,4-Dimethoxy-3-(3-methyl-but-2-enyl)-benzoyl]-5-(2,4-dimethoxy-phenyl)-3-methyl-cyclohex-2-enyl]-2-(2,4-dimethoxy-phenyl)-5,7-dimethoxy-3-(3-methyl-but-2-enyl)-chromen-4-one 

Downstream Products

• 76851-98-4 8-[(1S,5R,6S)-6-[2,4-Dimethoxy-3-(3-methyl-but-2-enyl)-benzoyl]-5-(2,4-dimethoxy-phenyl)-3-methyl-cyclohex-2-enyl]-2-(2,4-dimethoxy-phenyl)-5,7-dimethoxy-3-(3-methyl-but-2-enyl)-chromen-4-one 
• 79056-47-6 8-[(1R,5R,6S)-6-[2,4-Dimethoxy-3-(3-methyl-but-2-enyl)-benzoyl]-5-(2,4-dimethoxy-phenyl)-3-methyl-cyclohex-2-enyl]-2-(2,4-dimethoxy-phenyl)-5,7-dimethoxy-3-(3-methyl-but-2-enyl)-chromen-4-one 

Relevant academic research and scientific papers

Chiral Boron Complex-Promoted Asymmetric Diels-Alder Cycloaddition and Its Application in Natural Product Synthesis

An efficient method for the asymmetric Diels-Alder cycloaddition of 2'-hydroxychalcones with acyclic or cyclic dienes has been successfully developed. The Diels-Alder cycloaddition is mediated by a chiral boron complex with VANOL, affording the corresponding products in high yields and with excellent diastereo- and enantioselectivities. This reaction enabled the enantioselective construction of cyclohexene skeletons crucial for the total synthesis of a number of Diels-Alder-type natural products (-)-nicolaioidesin C, (-)-panduratine A, (-)-kuwanon I, (+)-kuwanon J, and (-)-brosimones A and B.

CHALCOMORACIN, A NATURAL DIELS-ALDER ADDUCT FROM DISEASED MULBERRY

The structure elucidation of a new phytoalexin, isolated from diseased mulberry leaves and designated as chalcomoracin, is described.The compound is regarded biogenetically as a Diels-Alder adduct of a chalcone, isolated newly from diseased mulberry shoot

ALBANINS F AND G, NATURAL DIELS-ALDER ADDUCTS FROM MULBERRY

The structure elucidation of albanins F and G, two of the preexisting antifungal principles of shoot epidermis of mulberry, is described.