76490-68-1Relevant academic research and scientific papers
Selective catalytic monoreduction of dichlorooligosilanes with Grignard reagents
Kanno, Ken-ichiro,Niwayama, Yuka,Kyushin, Soichiro
, p. 6940 - 6943 (2013)
Transition metal-catalyzed monoreduction of dichlorooligosilanes with Grignard reagents is reported. Among the examined catalysts, group 4 metal chlorides such as TiCl4 and Cp2TiCl2 gave the highest reactivity and good selectivity. The reducing power is effectively controlled by changing the catalysts and Grignard reagents to achieve sufficient selectivity depending on the oligosilane substrates.
Chloroplatinic acid catalyzed cyclization of silanes bearing pendant acetylenic groups
Steinmetz, Mark G.,Udayakumar, B. S.
, p. 1 - 16 (2007/10/02)
Chloroplatinic acid catalyzed, intramolecular hydrosilylation of acetylenes of structure HMe2SinSiMe2CCR (R = H or Ph, n = 2 or 3) proceeds via syn addition of the Si-H group to the carbon triple bond to give, predominantly, cyclic products having an
