76503-52-1Relevant academic research and scientific papers
Synthetic Control by Internal Interaction. The Intramolecular Diels-Alder Reactions of Furan Derivatives and α,β-Unsaturated Amides
Takebayashi, Toyonori,Iwasawa, Nobuharu,Mukaiyama, Teruaki
, p. 1107 - 1112 (2007/10/02)
An efficient method for the acceleration of the intramolecular Diels-Alder reaction was established utilizing the internal interaction - the internal hydrogen bonding and the internal coordination of a magnesium salt. The intramolecular Diels-Alder reacti
TRANSITION METAL COMPLEXES AS CATALYSTS IN DIELS-ALDER REACTIONS.
Bailey, Mark S.,Brisdon, Brian J.,Brown, David W.,Stark, Kate M.
, p. 3037 - 3040 (2007/10/02)
Molybdenum and tungsten complexes of the type 3-allyl)(NCMe)2> are shown to catalyse intramolecular Diels-Alder reactions.The stereochemistry of one of the cyclo-adducts is confirmed by nOe measurements at 400 MHz.
SYNTHETIC CONTROL BY INTERNAL HYDROGEN BONDING. THE INTRAMOLECULAR DIELS-ALDER REACTION OF NITROFURAN AND α,β-UNSATURATED CARBOXAMIDES
Mukaiyama, Teruaki,Takebayashi, Toyonori
, p. 1013 - 1016 (2007/10/02)
The intramolecular Diels-Alder reaction of N-(5-nitrofurfuryl)-N-(2-hydroxyphenyl) α,β-unsaturated carboxamides gives good yields of cycloadducts when internal hydrogen bonding is present.
