7651-11-8Relevant academic research and scientific papers
Rh2(OAc)4-catalyzed formation of trans-alkenes from the reaction of aldehydes with perfluorophenyl diazomethane through tellurium ylide
Zhu, Shifa,Xing, Chunhui,Pang, Wan,Zhu, Shizheng
, p. 5897 - 5900 (2007/10/03)
Rh2(OAc)4 can catalyze the formation of perfluorophenyl-containing trans-epoxides from the reactions of perfluorophenyl diazomethane with activated aryl aldehydes through sulfur ylide intermediate. In contrast, under the same reactio
Laser flash photolysis study of phenylcarbene and pentafluorophenylcarbene
Admasu, Atnaf,Gudmundsdottir, Anna Dora,Platz, Matthew S.
, p. 3832 - 3840 (2007/10/03)
Laser flash photolysis (LFP) (XeCl, 308 nm, 17 ns) of phenyldiazomethane and pentafluorophenyldiazomethane releases phenylcarbene (PC) and pentafluorophenylcarbene (PFPC), respectively. In acetonitrile solvent the carbenes react rapidly to form nitrile yl
Synthesis of (Pentafluorophenyl)diazomethane and 1-(Pentafluorophenyl)diazoethane
Meese, Claus O.
, p. 1711 - 1714 (2007/10/02)
The synthesis of the two new fluorinated diazoalkanes 2a and b is described.
