765319-28-6

Basic information

• Product Name: (1S,6R)-6-benzoylcyclohex-3-ene-1-carboxylic acid
• Synonyms: (1S,6R)-6-benzoylcyclohex-3-ene-1-carboxylic acid
• CAS NO: 765319-28-6
• Molecular Weight: 230.263
• Mol File: 765319-28-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (1S,6R)-6-benzoylcyclohex-3-ene-1-carboxylic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,6R)-6-benzoylcyclohex-3-ene-1-carboxylic acid(765319-28-6)
• EPA Substance Registry System: (1S,6R)-6-benzoylcyclohex-3-ene-1-carboxylic acid(765319-28-6)

Safety Data

• Hazardous Substances Data: 765319-28-6(Hazardous Substances Data)

Upstream product

• 146388-97-8 methyl (1S,6R)-6-benzoylcyclohex-3-enecarboxylate 
• 31139-02-3 (1R,6S)-6-methoxycarbonyl-3-cyclohexene-1-carboxylic acid 
• 935-79-5 cis-1,2,3,6-tetrahydrophthalic anhydride 
• 31211-31-1 racemic cis-6-benzoylcyclohex-3-enecarboxylic acid 
• 857682-04-3 (1S,6R)-6-benzoyl-1-[(4S)-4-isopropyl-1,3-thiazolidine-2-thion-3-yl]carbonylcyclohex-3-ene 
• 1078-58-6 diphenylzinc 

Downstream Products

• 146388-97-8 methyl (1S,6R)-6-benzoylcyclohex-3-enecarboxylate 

Relevant articles and documents

A palladium-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides

Monoalkylation of cyclic anhydrides provides an opportunity to couple a carbon-carbon bond-forming event with the control of backbone stereochemistry. We have developed a palladium-JOSIPHOS catalyst system that desymmetrizes meso-succinic anhydrides using organozinc reagents as nucleophiles, and have found that, in many cases, this reaction proceeds at ambient temperature. Copyright

Selective substituent transfer from mixed zinc reagents in Ni-catalyzed anhydride alkylation

(Chemical Equation Presented) The use of mixed zinc reagents in Ni-catalyzed anhydride alkylation results in preferential transfer of substituents (Ph > Me > Et ? iPr ～ TMSCH2) for the ligands bipy, dppe, and iPrPHOX. Utilization of such mixed