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Di-isophorone and Related Compounds. Part 6. The Action of Nucleophiles on 8-Bromodi-isophorone
Davies, Paul R.,Kurzer, Frederick,Morgan, Alan R.
, p. 1097 - 1110 (2007/10/02)
Hydrolysis and acetolysis of 8-bromo-1-hydroxydi-isophor-2(7)-en-3-one yields both epimeric forms of the corresponding 4-hydroxy and 4-acetoxy compounds, probably by a mechanism involving a bimolecular (SN2'') displacement.The action of excess of hydrazin
