76573-29-0

Upstream product

• 104-83-6 1-Chloro-4-(chloromethyl)benzene 
• 97-30-3 methyl D-glucopyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 76573-30-3 methyl 2,3,4,6-tetra-O-(p-chlorobenzyl)-α-D-glucopyranoside 

Downstream Products

• 74426-44-1 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-(2,4-dinitro-phenylamino)-6-[(3R,4S,5R,6R)-3,4,5-tris-(4-chloro-benzyloxy)-6-(4-chloro-benzyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester 
• 74426-44-1 Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-5-(2,4-dinitro-phenylamino)-6-[(2S,3R,4S,5R,6R)-3,4,5-tris-(4-chloro-benzyloxy)-6-(4-chloro-benzyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester 
• 74426-44-1 Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-5-(2,4-dinitro-phenylamino)-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-(4-chloro-benzyloxy)-6-(4-chloro-benzyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester 
• 14510-04-4 (2R,3R,4S,5S,6R)-2-((2S,3R,4R,5S,6R)-3-Amino-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol 
• 80081-18-1 (2R,3S,4R,5R,6S)-5-(2,4-Dinitro-phenylamino)-2-hydroxymethyl-6-[(2S,3R,4S,5R,6R)-3,4,5-tris-(4-chloro-benzyloxy)-6-(4-chloro-benzyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-3,4-diol 
• 80035-28-5 (2R,3S,4R,5R,6S)-5-(2,4-Dinitro-phenylamino)-2-hydroxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-(4-chloro-benzyloxy)-6-(4-chloro-benzyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-3,4-diol 
• 80035-28-5 (2R,3S,4R,5R,6R)-5-(2,4-Dinitro-phenylamino)-2-hydroxymethyl-6-[(3R,4S,5R,6R)-3,4,5-tris-(4-chloro-benzyloxy)-6-(4-chloro-benzyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-3,4-diol 
• 80081-37-4 (2R,3S,4R,5R,6R)-5-Amino-2-hydroxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-(4-chloro-benzyloxy)-6-(4-chloro-benzyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-3,4-diol 
• 80035-29-6 (2R,3S,4R,5R,6S)-5-Amino-2-hydroxymethyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-(4-chloro-benzyloxy)-6-(4-chloro-benzyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-3,4-diol 
• 80035-29-6 (2R,3S,4R,5R,6R)-5-Amino-2-hydroxymethyl-6-[(2S,3R,4S,5R,6R)-3,4,5-tris-(4-chloro-benzyloxy)-6-(4-chloro-benzyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-3,4-diol 

Relevant academic research and scientific papers

Gold-catalyzed synthesis of α-D-glucosides using an o-ethynylphenyl β-D-1-thioglucoside donor

A gold-catalyzed glucosylation method using an o-ethynylphenyl β-D-1-thioglucoside as donor is described. The reaction proceeds in a mostly SN2 pathway. A series of α-D-glucosides are obtained in good yields and with up to 19:1 α-selectivity.