76582-85-9Relevant academic research and scientific papers
INFLUENCE OF CATION COMPLEXING SOLVENT ADDITIVES AND FUNCTIONAL GROUPS IN ASYMMETRIC ALKYLATIONS OF ESTERS VIA LITHIUM ENOLATES
Helmchen, Guenter,Selim, Adel,Dorsch, Dieter,Taufer, Irmtraud
, p. 3213 - 3216 (2007/10/02)
Highly diastereoselective alkylations of propionates of chiral alcohols derived from (+)-camphor are described.It is demonstrated that steric shielding as well as cation complexation are important for stereoselection.The latter effects are in part rationa
