765910-61-0Relevant academic research and scientific papers
Diastereoselective synthesis of 5-hydroxy-8-methoxy-1-oxaspiro[5,5]undeca- 7,10-diene-9-one
Plourde, Guy L.,Scully, Thomas W.
, p. 1174 - 1180 (2013/04/10)
A short five steps synthesis of the title compound from vanillin is described. The racemic spiroether 7 was obtained in 61% yield and in >99% diastereomeric excess (by 1H-NMR) from the corresponding phenolic derivative 3 by oxidation with lead (IV) acetate.
Transition metals catalyzed C-C and C-O bonds formation: Facile synthesis of flavans and benzoxepines
Ramulu, B. Venkat,Mahendar,Krishna,Reddy, A. Gopi Krishna,Suchand,Satyanarayana
, p. 8305 - 8315 (2013/09/02)
A simple and practical method has been developed based on intermolecular [Pd]-catalyzed C-C and an intramolecular [Cu]-catalyzed C-O bond formations for the synthesis of flavans and benzoxepines. Interestingly, the method is amenable for the synthesis of
Mild and efficient allylation of aldehydes mediated by titanium(III) chloride
Jana, Samaresh,Guin, Chandrani,Roy, Subhas Chandra
, p. 6575 - 6577 (2007/10/03)
A mild, chemoselective and efficient method for the allylation of aldehydes is described. Ketones remained unreacted under the reaction conditions.
