765910-61-0Relevant academic research and scientific papers
Transition metals catalyzed C-C and C-O bonds formation: Facile synthesis of flavans and benzoxepines
Ramulu, B. Venkat,Mahendar,Krishna,Reddy, A. Gopi Krishna,Suchand,Satyanarayana
, p. 8305 - 8315 (2013/09/02)
A simple and practical method has been developed based on intermolecular [Pd]-catalyzed C-C and an intramolecular [Cu]-catalyzed C-O bond formations for the synthesis of flavans and benzoxepines. Interestingly, the method is amenable for the synthesis of
Diastereoselective synthesis of 5-hydroxy-8-methoxy-1-oxaspiro[5,5]undeca- 7,10-diene-9-one
Plourde, Guy L.,Scully, Thomas W.
, p. 1174 - 1180 (2013/04/10)
A short five steps synthesis of the title compound from vanillin is described. The racemic spiroether 7 was obtained in 61% yield and in >99% diastereomeric excess (by 1H-NMR) from the corresponding phenolic derivative 3 by oxidation with lead (IV) acetate.
Mild and efficient allylation of aldehydes mediated by titanium(III) chloride
Jana, Samaresh,Guin, Chandrani,Roy, Subhas Chandra
, p. 6575 - 6577 (2007/10/03)
A mild, chemoselective and efficient method for the allylation of aldehydes is described. Ketones remained unreacted under the reaction conditions.
