765936-39-8Relevant academic research and scientific papers
Synthesis and structural studies of phosphorus carbonyl manganacycles containing the tetraphenyldiselenoimidodiphosphinato ligand
Germán-Acacio, Juan Manuel,Reyes-Lezama, Marisol,Zú?iga-Villarreal, Noé
, p. 3223 - 3231 (2006)
The [Mn(CO)4-x(L){Ph2P(Se)NP(Se)Ph2-κ 2Se}] complexes, where x = 1 for L = PPh3 and PMePh2, and x = 2 for L = Ph2PCH2CH2PPh2 (diphos), were synth
Six-membered tetracarbonylmanganese(I) and -rhenium(I) metalacycles containing the [Ph2P(Se)NP(Se)Ph2] ligand: solution and solid state characterization
Zú?iga-Villarreal, Noé,Germán-Acacio, Juan Manuel,Lemus-Santana, Ana Adela,Reyes-Lezama, Marisol,Toscano, Rubén A.
, p. 2827 - 2832 (2004)
The halocarbonyls BrM(CO)5, M = Mn and Re, were reacted with the KN(SePPh2)2 salt in equimolar amounts; the reactions were thermally carried out and resulted in the generation of the hexacoordinated isostructural complexes [M(CO)4 {Ph2P(Se)NP(Se)Ph2- Se,Se′}] with a twist MSePNPSe ring conformation. Complexes' characterizations were achieved by IR, mass, NMR (1H, 133C, 31P, 77Se) spectroscopies, and by single-crystal X-ray diffraction.
