765943-54-2Relevant academic research and scientific papers
Cyclopropanation and carbonyl olefination utilizing 2-(Alk-1-yn-1-yl)-2- (trialkylsilyl)-1,3-dithianes via regioselective generation of titanium alkynylcarbene complexes
Takeda, Takeshi,Ozaki, Makoto,Kuroi, Shuichi,Tsubouchi, Akira
, p. 4233 - 4239 (2007/10/03)
Cp2Ti[P(OEt)3]2-promoted reactions of 2-(alk-1-yn-1-yl)-2-(trialkylsilyl)-1,3-dithianes (RS)2C(Si)C≡ CR with terminal olefins and carbonyl compounds produced (trialkylsilylethynyl) cyclopropanes and 1-(trialkyls
Trialkylsilyl group-directed regioselective transformations of 2-(alk-1-yn-1-yl)-2-(trialkylsilyl)-1,3-dithianes to alkynylcyclopropanes and enynes
Takeda, Takeshi,Kuroi, Shuichi,Ozaki, Makoto,Tsubouchi, Akira
, p. 3207 - 3210 (2007/10/03)
(Chemical Equation Presented) The Cp2Ti[P(OEt)3] 2-promoted reaction of 2-(alk-1-yn-1-yl)-2-(trialkylsilyl)-1,3- dithianes with 1-alkenes regioselectively produced [(trialkylsilyl)-ethynyl] cyclopropanes with a formal ally
