765952-17-8Relevant academic research and scientific papers
Inverse electron-demand aza-[4+2] cycloaddition reactions of allenamides
Berry, Craig R.,Hsung, Richard P.
, p. 7629 - 7636 (2007/10/03)
An inverse electron-demand aza-[4+2] cycloaddition reaction of allenamides with 1-azadiene is described here. Effects of solvents on diastereoselectivity along with synthetic scopes and mechanistic insights are illustrated. Despite some synthetic limitations, this aza-[4+2] cycloaddition does provide a useful template for the synthesis of aza-glycoside related heterocycles.
