76613-38-2

Upstream product

• 50780-12-6 N,N'-bis(1,1,3,3-tetramethylbutyl)thiadiaziridine 1,1-dioxide 
• 103-71-9 phenyl isocyanate 
• 76613-31-5 N-chloro-N,N'-bis(1,1,3,3-tetramethylbutyl)sulfamide 
• 6281-65-8 N,N'-bis(1,1,3,3-tetramethylbutyl)sulfamide 
• 76613-37-1 N-(1,1,3,3-Tetramethylbutyl)-N-(2,2,4,4-tetramethyltetramethylene)sulfamide 

Relevant academic research and scientific papers

Thiadiaziridine 1,1-Dioxides: Synthesis and Chemistry

The synthesis and chemical reactions of a series of thiadiaziridine 1,1-dioxides (2) are described.The thermal stability is highly dependent on the R group and in one case (R = tert-octyl) is postulated that the thermolysis initially produces a diradical intermediate which can be trapped or further fragments to give a nitrene.A temperature-dependent NMR study on the coalescence of the diastereotopic α-methyl protons of 2b gives a ΔG = 20 kcal*mol-1.