76620-38-7Relevant academic research and scientific papers
Palladium/Norbornene-Catalyzed ortho Aliphatic Acylation with Mixed Anhydride: Selectivity and Reactivity
Xu, Shibo,Jiang, Julong,Ding, Linlin,Fu, Yao,Gu, Zhenhua
, p. 325 - 328 (2018/01/27)
A palladium/norbornene-catalyzed ortho acylation for the efficient synthesis of functionalized alkyl aryl ketones is reported. Studies on the electronic and steric properties of mixed aryl anhydrides indicated that the cross-coupling favored with the elec
Lewis Acid Promoted Decomposition of Unsaturated α-Diazo Ketones. 3. Stereochemical Consequences of Polyolefinic Cyclizations Initiated by the α-Diazo Ketone Functionality
Smith, Amos B.,Dieter, R. Karl
, p. 2017 - 2022 (2007/10/02)
This report presents the stereochemical consequences of polyolefinic cyclizations initiated by Lewis acid decomposition of α-diazo ketones.Three diazo ketones (1, 2, and 5) were examined; each was found to undergo a nonstereospecific process leading eithe
