76622-36-1Relevant academic research and scientific papers
REACTION OF DIALKOXYPHOSPHORYL- AND THIOPHOSPHORYLSULFENYL BROMIDES WITH DIAZO COMPOUNDS
Khaskin, B. A.,Torgasheva, N. A.,Ishmuratov, A. S.
, p. 989 - 993 (2007/10/02)
Reaction of dialkoxyphosphoryl- and thiophosphorylsulfenyl bromides with diazocompounds leads to the insertion of methylene or substituted methylene groups at the S-Br bond of the sulfenylbromide.In the reaction of dialkoxyphosphorylsulfenyl bromides with ethyl diazoacetate, insertion of an ethoxycarbonyl group at the S-Br bond of the sulfenyl bromide is accompanied by phosphoryl/thiophosphoryl rearrangement.
