76638-51-2Relevant academic research and scientific papers
ONE POT SYNTHESIS OF α-BROMO AND α-IODO KETONES FROM EPOXIDES
Denis, J. N.,Krief, A.
, p. 1429 - 1430 (1981)
α-bromo and α-iodo ketones are obtained in good yield and in one pot by reaction of terminal and disubstituted epoxides with trimthylsilyl halides and further oxidation (CrO3/H2SO4).
STEPWISE CONVERSION OF OXIRANES TO ALLYLIC ALCOHOLS BY IODOTRIMETHYLSILANE AND DBU
Sakurai, Hideki,Sasaki, Koshi,Hosomi, Akira
, p. 2329 - 2332 (2007/10/02)
Iodotrimethylsilane, prepared from hexamethyldisilane and iodine, reacts smoothly with oxiranes to give (2-iodoalkoxy)trimethylsilanes which can be converted to allylic alcohols with DBU in good yields.The whole conversion can be carried out in one-pot operation.
