76682-78-5Relevant academic research and scientific papers
Structural comparison of CuI and CuII complexes displaying analogous N2S2 co-ordination; x-ray analyses of tetraco-ordinate [Cu(pma)]BPh4 and pentaco-ordinate [Cu(pma)SO 4] [pma = 2-pyridylmethylbis-(2-ethylthioethyl)amine]
Karlin, Kenneth D.,Dahlstrom, Phillip L.,Hyde, Jeffrey R.,Zubieta, Jon
, p. 906 - 908 (1980)
The synthesis and X-ray structural characterization of the CuI and CuII complexes [Cu(pma)]BPh4 and [Cu(pma)SO 4] [pma = 2-pyridylmethylbis-(2-ethylthioethyl)amine] are reported, both display N2S2 co-ordination with the CuI complex exhibiting trigonal pyramidal geometry while the CuII derivative shows a distorted trigonal bipyramidal geometry which includes a co-ordinated sulphate group.
