76687-39-3Relevant articles and documents
METALLKOMPLEXE VON CYCLOPHANEN V. REAKTION VON 2,6,15,19-TETRATHIAPARACYCLOPHAN MIT Cr(CO)6. EINE NEUE MOEGLICHKEIT DER SCHWEFELEXTRUSION AUS EINEM THIAPHAN
Koray, Ali R.,Ziegler, Manfred L.
, p. 13 - 22 (1980)
The reaction of 2,6,15,19-tetrathiaparacyclophane with Cr(CO)6 is described.The reaction products demonstrate the tendency of the 1,3-propanedithia unit to be cleaved off under the influence of the metal carbonyl.The reaction products allow a radical mechanism to be proposed for the elimination of the 1,3-propanedithia unit.