76691-91-3Relevant academic research and scientific papers
Synthesis of 3-Phenoxybenzyl 1R-trans-2,2-Dimethyl-3-(2-phenyl/p-substitutedphenylprop-1-enyl)cyclopropanecarboxylates from (+)-3-Carene
Naik, R. H.,Kulkarni, G. H.,Mitra, R. B.
, p. 154 - 158 (2007/10/02)
Reaction of phenylmagnesium bromide with ketone V affords the alcohol (VIa) which on oxidation gives the hydroxy acid (VIIa, R = H), characterised through its methyl ester (VIIa, R = CH3).Epimerization of VIIa followed by esterification furnishes the tran
Synthesis of Methyl 1R(+)-cis-Chrysanthemate and Methyl 1S(+)-cis-2,2-Dimethyl-3-(2-phenylprop-1-enyl)cyclopropane-1-carboxylate from (+)-Car-3-ene
Bhat, N. G.,Mane, B. M.,Kulkarni, G. H.,Mitra, R. B.
, p. 204 - 206 (2007/10/02)
Synthesis of (+)-dihydrochrysanthemolactone (III), methyl 1R(+)-cis-chrysanthemate (II) and methyl 1S(+)-cis-2,2-dimethyl-3-(2-phenylprop-1-enyl)cyclopropane-1-carboxylate (XIII) has been achieved from a common intermediate 2,2-dimethyl-3-(2-methyl-2-hydroxypropyl)-cis-1-acetonylcyclopropane (IV), which is obtainable from (+)-car-3-ene by a known procedure.
New Synthesis of Methyl 1R-cis-(-)-2,2-Dimethyl-3-(2-phenylprop-1-enyl)cyclopropanecarboxylate and Methyl (+)-cis-Chrysanthemate from (+)-Car-3-ene
Bhat, N. G.,Joshi, G. D.,Gore, K. G.,Kulkarni, G. H.,Mitra, R. B.
, p. 558 - 561 (2007/10/02)
The syntheses of methyl 1R-cis-(-)-2,2-dimethyl-3-(2-phenylprop-1-enyl)cyclopropanecarboxylate (I) and methyl (+)-cis-chrysanthemate (II) have been achieved from 2,2-dimethyl-3-(2-methylprop-1-enyl)-cis-1-acetonylcyclopropane (IV) which can be obtained from (+)-car-3-ene (III) via the ketal ester, methyl 2,2-dimethyl-3-(2,2-ethylenedioxypropyl)cyclopropane-cis-1-acetate.
