767288-35-7Relevant academic research and scientific papers
Tris(trimethylsilyl)silane: An unprecedented enhancement in the diastereoselectivity of radical cyclisations to give 2,4-disubstituted piperidines
Gandon, Lucile A.,Russell, Alexander G.,Snaith, John S.
, p. 2270 - 2271 (2007/10/03)
Cyclisation of bromides 4a-f mediated by tributyltin hydride affords predominantly the trans piperidines 5a-f with modest diastereomeric ratios, while cyclisation with tris(trimethylsilyl)silane affords the same products with diastereomeric ratios of up t
