767319-38-0Relevant articles and documents
Total synthesis of polypropionate natural products: Application of new sulfur dioxide chemistry
Craita,Bouchez,Turks,Huang,Fonquerne,Murcia,Vogel
, p. 1223 - 1228 (2007/10/03)
In the presence of a Lewis or protic acid at low temperature, electron-rich dienes add to sulfur dioxide and carbon nucleophiles generating silyl sulfinates. The latter can be transformed into valuable polyketide precursors. Copyright Taylor & Francis Inc
First asymmetric synthesis of the cyclohexanone subunit of baconipyrones A and B. Revision of its structure
Turks, Maris,Murcia, M. Carmen,Scopelliti, Rosario,Vogel, Pierre
, p. 3031 - 3034 (2007/10/03)
(Chemical Equation Presented) An asymmetric synthesis of the 3,5-dihydroxycyclohexanone subunit of baconipyrones A and B, as well as that of the hydroxydiketone subunit of baconipyrones C and D ((-)-(4S,6S)-4,6-dimethyl- 5-hydroxynonan-3,7-dione), is desc