767319-40-4

Basic information

• Product Name: (-)-(1Z,2S,3R,4R)-1-ethylidene-2,4-dimethyl-5-oxo-3-((1S)-1-phenylethoxy)-heptyl isobutyrate
• Synonyms: (-)-(1Z,2S,3R,4R)-1-ethylidene-2,4-dimethyl-5-oxo-3-((1S)-1-phenylethoxy)-heptyl isobutyrate
• CAS NO: 767319-40-4
• Molecular Weight: 374.521
• Mol File: 767319-40-4.mol

Chemical Properties

• CAS DataBase Reference: (-)-(1Z,2S,3R,4R)-1-ethylidene-2,4-dimethyl-5-oxo-3-((1S)-1-phenylethoxy)-heptyl isobutyrate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(1Z,2S,3R,4R)-1-ethylidene-2,4-dimethyl-5-oxo-3-((1S)-1-phenylethoxy)-heptyl isobutyrate(767319-40-4)
• EPA Substance Registry System: (-)-(1Z,2S,3R,4R)-1-ethylidene-2,4-dimethyl-5-oxo-3-((1S)-1-phenylethoxy)-heptyl isobutyrate(767319-40-4)

Safety Data

• Hazardous Substances Data: 767319-40-4(Hazardous Substances Data)

Upstream product

• 51425-54-8 (Z)-3-trimethylsiloxy-2-pentene 
• 767319-35-7 (-)-(1E,3Z)-2-methyl-1-((1S)-1-phenylethoxy)penta-1,3-dien-3-ol isobutyrate 
• 681144-32-1 Trimethyl-{(Z)-1-[(E)-1-methyl-2-((S)-1-phenyl-ethoxy)-vinyl]-propenyloxy}-silane 

Downstream Products

• 767319-50-6 (-)-(1R,2R,3R,4R,5R,6R)-1-ethyl-2,4,6-trimethyl-5-((1S)-1-phenylethoxy)cyclohexan-1,3-diol 
• 767319-48-2 (2S,3S,4R,5S,6S)-3-Ethyl-3-hydroxy-2,4,6-trimethyl-5-((S)-1-phenyl-ethoxy)-cyclohexanone 

Relevant articles and documents

Expeditious asymmetric synthesis of a stereoheptad corresponding to the C(19)-C(27)-ansa chain of rifamycins: Formal total synthesis of rifamycin S

In the presence of sulfur dioxide and an acid promoter, (-)-(1E,3Z)-2-methyl-1-((1S)-1-phenylethoxy)penta-1,3-dien-3-yl isobutyrate reacts with (Z)-3-(trimethylsilyloxy)-pent-2-ene giving a silyl sulfinate intermediate that undergoes, in the presence of p

Total synthesis of polypropionate natural products: Application of new sulfur dioxide chemistry

In the presence of a Lewis or protic acid at low temperature, electron-rich dienes add to sulfur dioxide and carbon nucleophiles generating silyl sulfinates. The latter can be transformed into valuable polyketide precursors. Copyright Taylor & Francis Inc

First asymmetric synthesis of the cyclohexanone subunit of baconipyrones A and B. Revision of its structure

(Chemical Equation Presented) An asymmetric synthesis of the 3,5-dihydroxycyclohexanone subunit of baconipyrones A and B, as well as that of the hydroxydiketone subunit of baconipyrones C and D ((-)-(4S,6S)-4,6-dimethyl- 5-hydroxynonan-3,7-dione), is desc