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[Ru(CO)2Cl(η-C3H5)(AsPh3)] is a complex organometallic compound containing ruthenium as the central metal atom. It features two carbonyl ligands (CO), one chloride ligand (Cl), one η-allyl ligand (η-C3H5), and one triphenylarsine ligand (AsPh3). The η-allyl ligand is a three-carbon chain that is bonded to the ruthenium atom through two of its carbon atoms, while the triphenylarsine ligand is a bulky, electron-rich ligand that can influence the electronic properties and reactivity of the complex. [Ru(CO)2Cl(η-C3H5)(AsPh3)] is of interest in the field of organometallic chemistry and catalysis, as it can be used in various chemical transformations and reactions.

76736-31-7

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76736-31-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 76736-31-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,6,7,3 and 6 respectively; the second part has 2 digits, 3 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 76736-31:
(7*7)+(6*6)+(5*7)+(4*3)+(3*6)+(2*3)+(1*1)=157
157 % 10 = 7
So 76736-31-7 is a valid CAS Registry Number.

76736-31-7Downstream Products

76736-31-7Relevant academic research and scientific papers

PREPARATION, MECHANISM OF FORMATION, STRUCTURE, AND REACTIONS OF η-ALLYL COMPLEXES OF RUTHENIUM(II)

Barnard, Christopher F. J.,Daniels, J. Anthony,Holland, Philip R.,Mawby, Roger J.

, p. 2418 - 2424 (2007/10/02)

Reaction of either of two isomers of or either of two isomers of 2> with SnBu3(C3H5) yields a single isomer of .A mechanism involving the intermediate formation of the five-co-ordinate species and is proposed for the reactions.Treatment of complexes 2> (L = phosphorus or arsenic ligand) with SnBu3(C3H5) yields the related complexes , and the method can be extended to the preparation of 1-methylallyl and 2-methylallyl complexes.Simulation of the complex (1)H n.m.r. spectra of and its AsMe2Ph analogue provides detailed information about the coupling between the protons in the allyl ligand.Treatment of with excess of PMe2Ph results in the formation of , which is very slowly converted in solution into : the key intermediate in the system appears to be .

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