76771-01-2

Basic information

• Product Name: Ir(CH₂CHCH₂)Br(C₉H₆NO)(CO)(P(C₆H₅)3)
• CAS NO: 76771-01-2
• Molecular Weight: 747.651
• Mol File: 76771-01-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ir(CH₂CHCH₂)Br(C₉H₆NO)(CO)(P(C₆H₅)3)(CAS DataBase Reference)
• NIST Chemistry Reference: Ir(CH₂CHCH₂)Br(C₉H₆NO)(CO)(P(C₆H₅)3)(76771-01-2)
• EPA Substance Registry System: Ir(CH₂CHCH₂)Br(C₉H₆NO)(CO)(P(C₆H₅)3)(76771-01-2)

Safety Data

• Hazardous Substances Data: 76771-01-2(Hazardous Substances Data)

Upstream product

• 2872-54-0 sodium 8-quinolinolate 

Relevant articles and documents

8-OXYQUINOLATE IRIDIUM(I) COMPLEXES AND THEIR OXIDATIVE-ADDITION REACTIONS

The novel sixteen-electron complex (Oq = 8-oxyquinolate; COD = 1,5-cyclooctadiene) adds monodentate phosphines, phosphites or activated olefins irreversibly to give pentacoordinate iridium(I) complexes of the type (L = PPh3, P(OPh)3, maleic anhydride or tetracyanoethylene).Reaction of with some diphosphines leads to substitution products of the general formula (diphos = 1,2-bis(diphenylphosphino)ethane or cis-1,2-bis(diphenylphosphino)ethylene).Carbon monoxide displaces the COD group from the complexes giving either or , and the latter undergo oxidative addition reactions with SnCl4, Me3SiCl, Me3SnCl, MeI, allylbromide, PhCOCl, MeCOCl, Cl2, Br2, TlCl3 and HCl leading to novel iridium (III) complexes.