76779-61-8Relevant academic research and scientific papers
SYNTHESIS OF AN OCTAMETHYL-18-CROWN-6 DERIVATIVE AND THE X-RAY CRYSTAL STRUCTURE OF ITS 2:1 COMPLEX WITH BORANE-AMMONIA
Alston, David R.,Stoddart, J. Fraser,Wolstenholme, John B.,Allwood, Billy L.,Williams David J.
, p. 2923 - 2926 (1985)
The synthesis of 2,2,3,3,11,11,12,12-octamethyl-1,4,7,10,13,16-hexaoxacyclooctadecane (2) from pinacol (3) by a sequence of reactions (3->4->5->6+5->2) involving alkylation (3->4), ozonolysis and reduction (4->5), tosylation (5->6), and cyclisation (5+6->
Design and synthesis of a more highly selective ammonium ionophore than nonactin and its application as an ion-sensing component for an ion-selective electrode
Suzuki, Koji,Siswanta, Dwi,Otsuka, Takeshi,Amano, Tsuyoshi,Ikeda, Takafumi,Hisamoto, Hideaki,Yoshihara, Ryoko,Ohba, Shigeru
, p. 2200 - 2205 (2000)
A novel ammonium ionophore, which exhibits superior NH4+ selectivity compared with that of the natural antibiotic nonactin, was successfully designed and synthesized based on a 19-membered crown compound (TD19C6) having three decalin
Design and synthesis of sodium ion-selective ionophores based on 16-crown-5 derivatives for an ion-selective electrode
Suzuki, Koji,Sato, Kazunari,Hisamoto, Hideaki,Siswanta, Dwi,Hayashi, Kazuo,Kasahara, Noriko,Watanabe, Kazuhiko,Yamamoto, Noriko,Sasakura, Hideshi
, p. 208 - 215 (2007/10/03)
To develop an ionophore that is highly selective for sodium for use in an ion-selective electrode, we propose a model based on 16-crown-5 which has a cavity just the size of Na+ and has a "block" subunit to prevent complex formation with ions l
