76782-69-9Relevant academic research and scientific papers
Synthesis of tertiary propargylic phosphonates by addition of trialkynylaluminum reagents to acyl phosphonates and investigation of their antimicrobial activities
Hossain, Mohammad Shakhawoat,Demir, Ayhan Sitki,Cakir, Sidika Polat,Karaduman, Ayse Betul,Yamac, Mustafa
, p. 880 - 893 (2014)
A series of propargylic alcohols containing phosphonates was synthesized by addition reactions of tris- (propynyl) and tris-(phenylethynyl)aluminum reagents to acyl phosphonates in good yields. Aromatic moieties of the acyl phosphonates with electron-with
Novel Synthetic Aspects of the Phosphonate-Phosphate Rearrangement, 1. An Useful Approach to 1,2-Propadienyl Phosphates
Hammerschmidt, Friedrich,Schneyder, Elisabeth,Zbiral, Erich
, p. 3891 - 3897 (2007/10/02)
Acyclphosphonates 1 react with 1-alkynes 2 in toluene to give dialkyl (1-hydroxy-2-alkynyl)phosphonates 3.These rearrange in alcohol/sodium alkoxide to 2-propynyl phosphates 4 and 1,2-propadienyl phosphates 5.Using dimethyl sulfoxide/sodium bis(trimethyls
