76793-02-7 Usage
Chemical structure
A complex bicyclic ring system with a piperidine group and a hydroxyl group.
Functional groups
Contains a hydroxyl (-OH) group, which may contribute to its potential reactivity and applications.
Substituents
Features three methyl groups (-CH3) attached to the bicyclic structure, which can influence its steric properties and potential interactions with other molecules.
Potential applications
May have uses in pharmaceuticals or organic synthesis due to its unique structure and functionality.
Further investigation
The specific properties and potential applications of 1,3,3-trimethyl-6-(piperidin-1-yl)-2-oxabicyclo[2.2.2]octan-5-ol would need to be further explored and studied to fully understand its capabilities and limitations.
Stereochemistry
The compound may exhibit stereoisomerism, which could lead to different properties and applications depending on the spatial arrangement of its atoms.
Solubility
The solubility of 1,3,3-trimethyl-6-(piperidin-1-yl)-2-oxabicyclo[2.2.2]octan-5-ol in various solvents (e.g., water, organic solvents) may be an important factor to consider for its potential applications.
Stability
The stability of the compound under different conditions (e.g., temperature, pH) may impact its suitability for specific applications.
Check Digit Verification of cas no
The CAS Registry Mumber 76793-02-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,6,7,9 and 3 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 76793-02:
(7*7)+(6*6)+(5*7)+(4*9)+(3*3)+(2*0)+(1*2)=167
167 % 10 = 7
So 76793-02-7 is a valid CAS Registry Number.
76793-02-7Relevant academic research and scientific papers
Carbonyl Transposition and Regio- and Stereo-specific Syntheses of New Alcohols, Amino-alcohols, and Ketones in the Monoterpenoid 1,3,3-Trimethyl-2-oxabicyclooctane
Bondavalli, Francesco,Schenone, Pietro,Ranise, Angelo,Lanteri, Silvia
, p. 2626 - 2630 (2007/10/02)
An efficient transposition of carbonyl group R1-CO-CH2-R2 -> R1-CH2-CO-R2 in the 1,3,3-trimethyl-2-oxabicyclooctane system was carried out via hydroboration-oxidation of 6-dialkylamino-1,3,3-trimethyl-2-oxabicyclooct-5-enes (3a-c), which gave regio- and stereo-specifically 6-cis-dialkylamino-1,3,3-trimethyl-2-oxabicyclooctan-5-trans-ols (4a-c) in high yield.Cope reaction on the N-oxide (5b) obtained from the amino-alcohol (4b) with hydrogen peroxide led to 1,3,3-trimethyl-2-oxabicyclooctan-5-one (6), the other possible isomer of the long-known 1,3,3-trimethyl-2-oxabicyclooctan-6-one (1b).The ketone (6) was also obtained from 1,3,3-trimethyl-2-oxabicyclooct-5-ene (2) via its trans-epoxide (11), lithium aluminium hydride reduction at 160-165 deg C of which gave stereo- and regio-specifically 1,3,3-trimethyl-2-oxabicyclooctan-5-trans-ol (9b).Chromic acid oxidation of (9b) and (4a-c) under various conditions gave the ketone (6) and the amino-ketones (7a-c), respectively.Lithium aluminium hydride reduction of (6) and (7a-c) afforded stereospecifically the cis-alcohol (9a) and 6-cis-dialkylamino-1,3,3-trimethyl-2-oxabicyclooctan-5-cis-ols (8a-c), respetively.Hydroboration-oxidation of the alkene (2) was not regiospecific, giving a 3:1 mixture of the trans-alcohols (9b) and (10b), respectively.
