76833-05-1Relevant academic research and scientific papers
Furanosyl Oxocarbenium Ion Conformational Energy Landscape Maps as a Tool to Study the Glycosylation Stereoselectivity of 2-Azidofuranoses, 2-Fluorofuranoses and Methyl Furanosyl Uronates
van der Vorm, Stefan,Hansen, Thomas,van Rijssel, Erwin R.,Dekkers, Rolf,Madern, Jerre M.,Overkleeft, Herman S.,Filippov, Dmitri V.,van der Marel, Gijsbert A.,Codée, Jeroen D. C.
supporting information, (2019/04/30)
The 3D shape of glycosyl oxocarbenium ions determines their stability and reactivity and the stereochemical course of SN1 reactions taking place on these reactive intermediates is dictated by the conformation of these species. The nature and co
Facile Synthesis of 2-Deoxy-2-substituted-D-arabinofuranose Derivatives
Su, Tsann-Long,Klein, Robert S.,Fox, Jack J.
, p. 1790 - 1792 (2007/10/02)
Several methyl 2-deoxy-2-substituted-D-arabinofuranosides (4a-e and 5b-e) to be used as intermediates in the synthesis of 2'-substituted arabinonucleosides of biomedical interest were prepared by treatment of methyl 3,5-di-O-benzyl-2-O-(trifluoromethanesu
