76834-32-7Relevant academic research and scientific papers
Rearrangements of Vinylogous Acyl Chlorides, XXVI. - Z,E-Isomerizations of S-Alkyl and S-Aryl 2,3,4,5-Tetrachloro-2,4-pentadienethioates via 2H-Pyran Intermediates
Roedig, Alfred,Fleischmann, Klaus
, p. 1960 - 1971 (2007/10/02)
The (Z,Z)-thioates 2 are prepared from the acyl chlorides 1 with thiols and triethylamine in ether or with thiolates in ethanol.They are stable below 100 deg C.At higher temperature the alkyl esters 2a - c and 2h, i lose alkyl chloride and decompose to th
