768398-16-9Relevant academic research and scientific papers
Catalytic enantioselective synthesis of alkenylhydrosilanes
Igawa, Kazunobu,Yoshihiro, Daisuke,Ichikawa, Nobumasa,Kokan, Naoto,Tomooka, Katsuhiko
, p. 12745 - 12748 (2012)
Asymmetric silanes: A synthesis of nonracemic alkenylhydrosilanes has been developed based on the desymmetrization of a dihydrosilane through alkenylation with an alkyne using an asymmetric catalyst. The alkenylhydrosilane product can be used as a versatile chiral building block for other functionalized nonracemic silanes through the stereoselective conversion of its hydride and/or alkenyl moiety. Copyright
Enantioselective synthesis of silanol
Igawa, Kazunobu,Takada, Junko,Shimono, Tomohiro,Tomooka, Katsuhiko
supporting information; experimental part, p. 16132 - 16133 (2009/05/08)
An enantioselective nucleophilic substitution reaction of achiral dialkoxysilane has been developed. The reaction proceeds with efficient stereocontrol on the silicon chirality center to give the enantioenriched silyl ether, which can be converted to the
