768402-60-4

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• 768402-58-0 [(1S,2S,3S,5R)-3-(diphenylphosphinoyl)-6,6-dimethylbicyclo[3.1.1]hept-2-yl]methanol 

Relevant academic research and scientific papers

Chiral diphosphinoterpenes and transition metal complexes thereof

The present invention relates to chiral diphosphinoterpenes and transition metal complexes thereof, to a process for preparing chiral diphosphinoterpenes and oxides thereof, and to transition metal complexes comprising the chiral diphosphinoterpenes. In a

Novel chiral diphosphine ligands with a pinene core obtained via an allylphosphinite-allylphosphine oxide rearrangement

A number of new chiral diphosphine ligands with a pinene framework were synthesized and tested in some transition metal-catalyzed asymmetric reactions (enantioselectivities up to 84% ee were achieved). The [2,3]-sigmatropic allylphosphinite-allyl phosphin