768402-63-7Relevant academic research and scientific papers
Chiral diphosphinoterpenes and transition metal complexes thereof
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Page/Page column 6; 10, (2010/02/14)
The present invention relates to chiral diphosphinoterpenes and transition metal complexes thereof, to a process for preparing chiral diphosphinoterpenes and oxides thereof, and to transition metal complexes comprising the chiral diphosphinoterpenes. In a
Novel chiral diphosphine ligands with a pinene core obtained via an allylphosphinite-allylphosphine oxide rearrangement
Gavryushin, Andrei,Polborn, Kurt,Knochel, Paul
, p. 2279 - 2288 (2007/10/03)
A number of new chiral diphosphine ligands with a pinene framework were synthesized and tested in some transition metal-catalyzed asymmetric reactions (enantioselectivities up to 84% ee were achieved). The [2,3]-sigmatropic allylphosphinite-allyl phosphin
