76859-40-0Relevant academic research and scientific papers
A reliable synthesis of 2- and 6-amino-β-cyclodextrin and permethylated-β-cyclodextrin
Muderawan, I. Wayan,Ong, Teng Teng,Teck, Chia Lee,Young, David J.,Chi, Bun Ching,Ng, Siu Choon
, p. 7905 - 7907 (2005)
A new, reliable method for the introduction of an amine group at positions 2 or 6 of β-cyclodextrin and permethyl-β-cyclodextrin is described. It involves selective tosylation followed by azide substitution and almost quantitative reduction with triphenylphosphine followed by hydrolysis of the phosphinimine intermediate.
The cyclodextrin-nicotinamide compound as a dehydrogenase model simulating apoenzyme-coenzyme-substrate ternary complex system
Kojima, Masayoshy,Toda, Fujio,Hattori, Kenjiro
, p. 2721 - 2724 (1980)
The cyclodextrin-dihydronicotinamide had a dihydronicotinamide group at the open side of cyclodextrin cavity, and showed a large rate enhancement in the reduction of substrate upon complexation comparing with NADH
The Regiospecific Mono Tosylation of Cyclodextrins
Onozuka, Shigeharu,Kojima, Masayoshi,Hattori, Kenjiro,Toda, Fujio
, p. 3221 - 3224 (2007/10/02)
α- and β-Cyclodextrins were tosylated with tosyl chloride in an alkaline solution.The products were confirmed to be monotosylated compounds, and the tosyl group was introduced at the C-3 position of one glucose unit of the cyclodextrin molecule.The 1:1 complex formation of cyclodextrin with tosyl chloride was observed spectrometrically.
