76870-88-7Relevant academic research and scientific papers
A ONE-STEP PREPARATION OF 2,3-ANHYDRO-4,6-O-BENZYLIDENE-α-D-ALLOPYRANOSIDE AND -GULOPYRANOSIDE
Mitsunobu, Oyo,Kudo, Takashi,Nishida, Mitsuru,Tsuda, Nobuo
, p. 1613 - 1614 (1980)
Methyl 4,6-O-benzylidene-α-D-glucopyranoside reacted with diethyl azodicarboxylate and triphenylphosphine to give methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside and -mannopyranoside with the former predominant, while allyl 4,6-O-bezylidene-α-D-galactopyranoside selectively afforded the corresponding 2,3-anhydroguloside.
