7690-75-7Relevant academic research and scientific papers
Total Synthesis of Linear Polyprenoids. 2. Improved preparation of the Aromatic Nucleus of Ubiquinone
Keinan, Ehud,Eren, Doron
, p. 3872 - 3875 (2007/10/02)
Highly efficient copper-catalyzed polymethoxylation of tribromocresol is the key process in a three-step, practical approach to obtain ubiquinone 0 from p-cresol.Short syntheses of several ubiquinones were achieved via direct, copper-mediated coupling of 2-lithio-3,4,5,6-tetramethoxytoluene to the appropriate polyprenyl bromide.
SYNTHESIS OF UBIQUINONES BY THE OXIDATIVE DEMETHYLATION OF UBIQUINOL MONOETHERS WITH CERIUM AMMONIUM NITRATE
Obol'nikova, E. A.,Kozlova, I. V.,Filippova, T. M.,Samokhvalov, G. I.
, p. 2027 - 2030 (2007/10/02)
Ubiquinone-9 and hexahydroubiquinone-4 were synthesized by oxidative demethylation of the corresponding ubiquinol monomethyl ethers with cerium ammonium nitrate.The stereochemistry of the double bond closest to the ring was investigated, and the contribut
