76916-67-1Relevant academic research and scientific papers
Copper-Catalyzed Regioselective and Diastereoselective Synthesis of Borylated 1-Benzo[ b]azepines
Li, Dingxi,Park, Yeji,Yun, Jaesook
supporting information, p. 7526 - 7529 (2019/01/03)
A practical regioselective and diastereoselective synthesis of functionalized 1-benzo[b]azepines by copper-catalyzed intramolecular cyclization has been developed. The reaction involves borylcupration of a mixture of (E/Z)-1,3-dienes, followed by capture
Palladium-Assisted N-Alkylation of Indoles: Attempted Application to Polycyclization
Hegedus, Louis S.,Winton, Peter M.,Varaprath Sudarsanan
, p. 2215 - 2221 (2007/10/02)
The palladium(II) complexes of the olefins ethene, propene, and 1-hexene reacted with 1-lithioindole to produce N-alkylated indoles exclusively.Attempts to perform this N-alkylation intramoleculary (to form tricyclic material from 2-allylskatole) failed.Anilines with dienic side chains in the 2-position were subjected to Pd(II)-assisted cyclization conditions in attempts to induce polycyclization.However, only monocyclization was observed.
