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Magnesium hydride, also known as MgH2, is a compound that contains 7.66% by weight of hydrogen and has been studied as a potential hydrogen-storage medium. It was discovered in 1912 during the pyrolysis of ethyl magnesium iodide, a Grignard reagent, which produced a small amount of MgH2. Magnesium hydride can be prepared through various methods, including direct hydrogenation of Mg metal at high pressure and temperature, hydrogenation of magnesium anthracene under mild conditions, the reaction of diethyl magnesium with LiAlH4, and the formation of an adduct of complexed MgH2.

7693-27-8

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7693-27-8 Usage

Uses

Used in Hydrogen Storage Applications:
Magnesium hydride is used as a hydrogen-storage medium due to its high hydrogen content and potential for energy storage. It offers advantages such as high energy density, low weight, and the ability to be produced at lower temperatures using nano-crystalline Mg.
Used in Chemical Industry:
In the chemical industry, magnesium hydride can be used as a reagent or intermediate in various chemical reactions. For example, it can be used in the preparation of other magnesium-containing compounds or as a reducing agent in certain chemical processes.
Used in Energy Storage and Conversion:
Magnesium hydride can be employed in energy storage and conversion systems, such as fuel cells and batteries, due to its ability to store and release hydrogen. This makes it a promising material for developing advanced energy storage technologies.
Used in Material Science:
In material science, magnesium hydride can be utilized in the development of new materials with unique properties. For instance, it can be incorporated into composite materials or used to create lightweight alloys with improved mechanical properties.
Overall, magnesium hydride is a versatile compound with a wide range of applications in various industries, including hydrogen storage, chemical industry, energy storage and conversion, and material science. Its unique properties and potential for energy storage make it a promising material for future technological advancements.

Air & Water Reactions

Highly flammable. Pyrophoric, ignites spontaneously in air and forms magnesium oxide and water [Merck 11th ed. 1989]. Reacts with water to form caustic solution of magnesium hydroxide and hydrogen gas (H2) and heat sufficient to ignite the evolved hydrogen [Merck 11th ed. 1989].

Reactivity Profile

Hydrides, such as Magnesium hydride, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols. Hydrides are incompatible with acids, alcohols, amines, and aldehydes.

Health Hazard

Inhalation or contact with vapors, substance or decomposition products may cause severe injury or death. May produce corrosive solutions on contact with water. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control may cause pollution.

Fire Hazard

Produce flammable gases on contact with water. May ignite on contact with water or moist air. Some react vigorously or explosively on contact with water. May be ignited by heat, sparks or flames. May re-ignite after fire is extinguished. Some are transported in highly flammable liquids. Runoff may create fire or explosion hazard.

Potential Exposure

Used in hydrogen production and in production of magnesium alcoholates.

Shipping

UN2010 Magnesium hydride, Hazard Class: 4.3; Labels: 4.3-Dangerous when wet material.

Incompatibilities

A strong reducing agent. Pyrophoric: the powder or dust may ignite spontaneously in air, or in the presence of moisture. Contact with water or steam forms magnesium hydroxide, flammable hydrogen gas, and enough heat to ignite the hydrogen. Violent reaction with oxidizers, alcohols, halogens, chlorinated solvents. Incompatible with strong acids, acid chlorides, alcohols, amines and aldehydes. Store under nitrogen. Decomposes @ 280C in high vacuum

Check Digit Verification of cas no

The CAS Registry Mumber 7693-27-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,6,9 and 3 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 7693-27:
(6*7)+(5*6)+(4*9)+(3*3)+(2*2)+(1*7)=128
128 % 10 = 8
So 7693-27-8 is a valid CAS Registry Number.
InChI:InChI=1/Mg.2H/q+2;2*-1

7693-27-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name Magnesium hydride

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7693-27-8 SDS

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