76984-97-9Relevant academic research and scientific papers
4,4-Dimethyl Effect. (1). Stereochemistries of the Hydrogenation Products of α-Onocerin
Tsuda, Yoshisuke,Sano, Takehiro
, p. 3134 - 3137 (2007/10/02)
Three isomeric hydrogenation products of α-onocerin diecetate, onoceranediol diacetates-I, -II, and III, were converted to the corresponding diones-I, -II, and -III, which exhibited a positive, a double humped, and a negative CD spectrum, respectively.The configurations of onocerane-I, -II, and -III were therefore elucidated as 8αH-14βH, 8αH-14αH, and 8βH-14αH, respectively.Keywords---α-onocerin; onoceranes; onocerane-3,21-diones; CD-spectra; 4,4-dimethyl effect; 4,4,10-trimethyl-trans-decalin-3-ones
