76994-90-6

Upstream product

• 79378-76-0 Methyl-2,3-di-O-benzyl-6-desoxy-4-O-(p-tolylsulfinyl)-α-D-glucopyranosid 
• 13225-27-9 2,3-Di-O-benzyl-4,6-di-O-methyl-sulfonyl-methyl-α-D-glucopyranosid 
• 98-59-9 p-toluenesulfonyl chloride 
• 536-57-2 p-toluene sulfinic acid 
• 56750-58-4 methyl 6-deoxy-2,3-bis-O-(phenylmethyl)-α-D-glucopyranoside 
• 17791-36-5 methyl 2,3-di-O-benzyl-α-D-glucopyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 100-44-7 benzyl chloride 
• 7177-79-9 methyl 2,3-di-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 3162-96-7 methyl 4,6-O-benzylidene-α-D-glucopyranoside 

Downstream Products

• 76994-91-7 Toluene-4-sulfonic acid (2R,3S,4R,5R,6S)-4,5-dihydroxy-6-methoxy-2-methyl-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

SYNTHESIS OF STEREOSPECIFICALLY LABELED CARBOHYDRATES II: PREPARATION OF (3S)- AND (3R)-ABEQUOSE

Preparation of methyl 3,6-dideoxy-D-xylo-hexapyranoside (methyl abequoside) having deuterium stereospecifically labeled at the 3S (1) and 3R (2) position, respectively, via three different routes is described.

Sugar Tosylates via p-Toluenesulfinic Acid Esters. - p-Toluenesulfinimidazolide - A Reagent for Formation of Sulfinic Acid Esters without Using Halides

The reaction of the protected sugar derivatives 1, 4, 7, 10, 13, 16, 19 and 20 with p-toluenesulfinimidazolide prepared from p-toluenesulfinic acid and N,N'-carbonyldiimidazole yields the corresponding p-toluenesulfinic esters 2, 5, 8, 11, 14, 17, 20 and 22.With the exception of 20 and 22, these products can be oxidized with m-chloroperbenzoic acid in high yields and short overall reaction times to the tosylates 3, 6, 9, 12, 15 and 18.