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The chemical compound [RhCl3(CO)(P(C2H5)2C6H5)(P(CH3)2C6H5)] is a rhodium-based complex with a coordination number of 6. It consists of a central rhodium atom coordinated to three chlorine atoms, one carbon monoxide (CO) ligand, and two phosphine ligands. The first phosphine ligand is diphenylphosphinoethane (P(C2H5)2C6H5), and the second is diphenylmethylphosphine (P(CH3)2C6H5). This complex is an example of a transition metal complex with a combination of halide, carbonyl, and phosphine ligands, which are common in organometallic chemistry and catalysis.

77018-12-3

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77018-12-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 77018-12-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,7,0,1 and 8 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 77018-12:
(7*7)+(6*7)+(5*0)+(4*1)+(3*8)+(2*1)+(1*2)=123
123 % 10 = 3
So 77018-12-3 is a valid CAS Registry Number.

77018-12-3Downstream Products

77018-12-3Relevant academic research and scientific papers

Direct Oxidative Addition-Reductive Elimination Reactions Between trans- and or trans- (M = Rh or Ir, L = tertiary phosphine)

Al-Jibori, Subhi,Crocker, Christopher,Shaw, Bernard L.

, p. 319 - 321 (2007/10/02)

Complexes of the type trans- and .M = Rh or Ir, L = PMe2Ph or PEt2Ph, have been shown to react with each other, presumably by a double chloro-bridged intermediate, and undergo rapid oxidative addition-reductive elimination; phosphine exchange is much slower.Similar results were obtained when trans- was treated with trans-, M = Rh or Ir, for which rapid and complete conversion into trans- and occured. (31)P NMR data are given.

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